RAS Chemistry & Material ScienceМеталлы Russian Metallurgy

  • ISSN (Print) 0869-5733
  • ISSN (Online) 3034-5391

ASPECTS OF CARBON DIOXIDE CORROSION IN MODERN PIPE STEELS

PII
S30345391S0869573325054351-1
DOI
10.7868/S3034539125054351
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume / Issue number 5
Pages
43-51
Abstract
This study investigates the corrosion behavior of pipe steels with chromium content up to 17% in CO-containing environments. Weight loss method was used to evaluate the key factors influencing corrosion processes, including temperature (up to 150 °C), CO partial pressure (up to 170 atm), chloride-ion concentration (up to 240 g/L), solution pH (3.5–7.5), and HS partial pressure (up to 0.5 atm). Results indicate that steels containing less than 1% Cr cannot provide required corrosion resistance. Increasing chromium content to 3–5% has a negligible effect on corrosion rates under these conditions, whereas steels with 13% Cr or higher demonstrate significantly improved resistance, even under highly aggressive conditions. This enhanced performance correlates with changes in the composition and protective properties of surface corrosion product layers. The findings establish application limits for steels with varying chromium content in CO environments and provide a foundation for material selection guidelines in extreme operating conditions.
Keywords
углекислотная коррозия скорость коррозии гравиметрический метод коррозионно-стойкие стали нелегированные стали
Date of publication
08.12.2025
Year of publication
2025
Number of purchasers
0
Views
19

References

  1. 1. Прыгаев, А.К. Анализ отказов промысловых трубопроводов и разработка метода защиты от коррозии / А.К. Прыгаев, Ю.С. Дубинов, М.С. Танасенко // Территория Нефтегаз. 2024. Т.3–4. @@Prygaev, A.K. Infield pipelines failure analysis and corrosion protection method development / A.K. Prygaev, Yu.S. Dubinov, M.S. Tanasenko // Oil and gas territory. 2024. V.3–4. P.60–65.
  2. 2. Щепинов, Д.Н. Анализ причин возникновения отказов газотранспортных систем / Д.Н. Щепинов, А.Е. Пятаев, В.М. Кушнаренко, Ю.А. Чирков // Проблемы сбора, подготовки и транспорта нефти и нефтепродуктов. 2016. Т.3. №105. @@Shchepinov, D.N. Analysis of the causes of gas transport system failures / D.N. Shchepinov, A.Ye. Pyatayev, V.M. Kushnarenko, Yu.A. Chirkov // Problems of Gathering, Treatment and Transportation of Oil and Oil Products. 2016. V.3. №105. P.110–118.
  3. 3. Пышминцев, И.Ю. Исследование коррозионной стойкости металла нефтегазопроводных труб с использованием электрохимических методов / И.Ю. Пышминцев, О.В. Вавилова, Е.Р. Мансурова, А.Н. Мальцева, С.А. Коробер // Металлург. 2023. №2. – @@Pyshmintsev, I.Yu. Electrochemical investigation of corrosion resistance of metal for oil and gas pipelines / I.Yu. Pyshmintsev, О.V. Vavilova, E.R. Mansurova, S.А. Korober, A.N. Maltseva // Metallurgist. 2023. V.67. №8.
  4. 4. Пумпянский, Д.А. Основы металловедения и технологии производства труб из коррозионно-стойких сталей / Д.А. Пумпянский, И.Ю. Пышминцев, А.В. Выдрин, В.И. Кузнецов, Красиков А.В. – М. : Металлургиздат, 2023. 682 @@Pumpyanskii, D.A. Fundamentals of materials science and production technology of corrosion-resistant steel pipes / D.A. Pumpyanskii, I.Yu. Pyshmintsev, A.V. Vydrin, V.I. Kuznetsov, A.V. Krasikov. – M. : Metallurgizdat, 2023. 682 p.
  5. 5. Царьков, А.Ю. Исследование защитного действия ингибиторов углекислотной коррозии в динамических условиях / А.Ю. Царьков, В.Ю. Роднова, О.А. Нечаева // Экспозиция Нефть Газ. 2021. Т.4. №83. @@Tsarkov, A.Yu. Investigation of the protective effect of carbon dioxide corrosion inhibitors under dynamic conditions / A.Yu. Tsarkov, V.Yu. Rodnova, O.A. Nechaeva // Exposition Oil & Gas. 2021. V.4. №83. P.54–56.
  6. 6. Пышминцев, И.Ю. Влияние содержания хрома в стали на коррозионную стойкость в углекислых средах / И.Ю. Пышминцев, А.Н. Мальцева, О.В. Вавилова, Т.М. Жучкова, С.И. Котов // Металлург. 2024. №12. C.7–15. – @@Pyshmintsev, I.Yu. Effect of chromium content in steel on corrosion resistance in carbon dioxide environments / I.Yu. Pyshmintsev, A.N. Maltseva, О.V. Vavilova, T.M. Zhuchkova, S.I. Kotov // Metallurgist. 2024. №12. P.7–15.
  7. 7. Lin, B. A study on the initiation of pitting corrosion in carbon steel in chloride-containing media using scanning electrochemical probes / B. Lin, R. Hu, C. Ye, Y. Li, C. Lin // Electrochim. Acta. 2010. V.55. №22. P.6542–6545.
  8. 8. Sun, J. Effect of Cr сontent on the electrochemical behavior of low-chromium X65 steel in CO2 environment / J. Sun, C. Sun, Y. Wang // Int. J. Electrochem. Sci. 2016. V.11. №10. P.8599–8611.
  9. 9. Вагапов, Р.К. Агрессивные факторы эксплуатационных условий, вызывающие коррозию на объектах добычи газа в присутствии диоксида углерода / Р.К. Вагапов, Д.Н. Запевалов // Практика противокоррозионной защиты. 2020. Т.25. №4. @@Vagapov, R.K. Aggressive environmental factors causing corrosion at gas production facilities in the presence of carbon dioxide / R.K. Vagapov, D.N. Zapevalov // Theory and Practice of Corrosion Protection. 2020. V.25. №4. P.7–17.
  10. 10. Пышминцев, И.Ю. Влияние сероводорода на углекислотную коррозию трубной стали / И.Ю. Пышминцев, А.Н. Мальцева, О.В. Вавилова, Е.Р. Мансурова, М.Ю. Павличев // Металлург. 2022. №9. C.78–83. – @@Pyshmintsev, I.Yu. Effect of hydrogen sulfide on pipe steel carbon dioxide corrosion / I.Yu. Pyshmintsev, A.N. Maltseva, O.V. Vavilova, E.R. Mansurova, M.Yu. Pavlichev // Metallurgist. 2023. V.66. №5. P.1–8.)
  11. 11. Choi, Y. Corrosion behavior of carbon steel in supercritical CO2-water environments / Y. Choi, S. Nesic // NACE – Int. Corros. Conf. Ser. 2009. №09256.
  12. 12. de Waard, C. Predictive model for CO2 corrosion engineering in wet natural gas pipelines / C. de Waard, U. Lotz, D.E. Milliams // Corrosion. 1991. V.47. №12. P.977–985.
  13. 13. Nesic, S. Key issues related to modelling of internal corrosion of oil and gas pipelines – A review / S. Nesic // Corros. Sci. 2007. V.49. №12. P.4308–4338.
  14. 14. Kahyarian, A. Electrochemistry of CO2 corrosion of mild steel: Effect of CO2 on iron dissolution reaction / A. Kahyarian, B. Brown, S. Nesic // Corros. Sci. 2017. V.129. P.146–151.
  15. 15. Sun, Y. A parametric study and modeling on localized CO2 corrosion in horizontal wet gas flow / Y. Sun, S. Nesic // Corrosion. 2004. №04380. P.1–24.
  16. 16. Bai, H. Effect of CO2 partial pressure on the corrosion behavior of J55 carbon steel in 30% crude oil/brine mixture / H. Bai, Y. Wang, Y. Ma, Q. Zhang, N. Zhang // Materials (Basel). 2018. V.11. №9. Art.1765.
  17. 17. Farelas, F. Corrosion behavior of deep water oil production tubing material under supercritical CO2 environment. Pt.2. Effect of crude oil and flow / F. Farelas, Y.S. Choi, S. Nesic, A. Magalhães, C. de Azevedo Andrade // Corrosion. 2014. V.70. №1. P.38–47.
  18. 18. Young, D. Construction and verification of pourbaix diagrams for CO2 corrosion of mild steel valid up to 250 °C / D. Young, B.N. Brown // NACE – Int. Corros. Conf. Ser. 2012.
  19. 19. Schlegel, M.L. Anodic activation of iron corrosion in clay media under water-saturated conditions at 90 °C : Characterization of the corrosion interface / M.L. Schlegel, C. Bataillon, C. Blanc, D. Prêt, E. Foy // Environ. Sci. Technol. 2010. V.44. №4. P.1503–1508.
  20. 20. Nesic, S. CO2 corrosion of carbon steel – From mechanistic to empirical modelling / S. Nesic, J. Postlethwaite, M. Vrhovac // Corros. Rev. 1997. V.15. №1–2. P.211–240.
  21. 21. Schmitt, G. Fundamental aspects of CO2 metal loss corrosion. Pt.II. Influence of different parameters on CO2 corrosion mechanism / G. Schmitt, M. Hörstemeier // NACE – Int. Corros. Conf. Ser. 2006. №06112.
  22. 22. Dugstad, А. The Importance of FeCO3 supersaturation on the CO2 corrosion of carbon steels corrosion / А. Dugstad // Corrosion. 1992. №14.
  23. 23. Zeng, Z. Effect of salt concentration on the corrosion behavior of carbon steel in CO2 environment / Z. Zeng, R.S. Lillard, H. Cong // Corrosion. 2016. V.72. №6. P.805–823.
  24. 24. Sani, F. M. An experimental investigation on the effect of salt concentration on uniform CO2 corrosion / F.M. Sani, B. Brown, Z. Belarbi, S. Nesic // NACE – Int. Corros. Conf. Ser. 2019. №13026.
  25. 25. Shoesmith, D.W. The formation of ferrous monosulfide polymorphs during the corrosion of iron by aqueous hydrogen sulfide at 21 °C / D.W. Shoesmith, P. Taylor, M.G. Bailey, D.G. Owen // J. Electrochem. Soc. 1980. V.127. №5. P.1007–1015.
  26. 26. Wikjord, A.G. Corrosion and deposition during the exposure of carbon steel to hydrogen sulphide-water solutions / A.G. Wikjord, T.E. Rummery, F.E. Doern, D.G. Owen // Corros. Sci. 1980. V.20. №5. P.651–671.
  27. 27. Yin, Z.F. Corrosion behavior of SM 80SS tube steel in stimulant solution containing H2S and CO2 / Z.F. Yin, W.Z. Zhao, Z.Q. Bai, Y.R. Feng, W.J. Zhou // Electrochim. Acta. 2008. V.53. №10. P.3690–3700.
QR
Translate

Индексирование

Scopus

Scopus

Scopus

Crossref

Scopus

Higher Attestation Commission

At the Ministry of Education and Science of the Russian Federation

Scopus

Scientific Electronic Library